
01-08-2018A high-quality perovskite film with low point defects and grain boundaries is necessary to obtain higher device PCEs. This could greatly avoid the non-radiative recombination which could cause the loss of open-circuit voltage ( V OC) and decreased carrier lifetime [ 17, 18, 19 ].
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A piece of the (FAPbI 3) 0.95 (CsPbBr 3) 0.05 perovskite film coated on a 4.8 9.6 cm 2 -substrate was used for testing the photovoltaic performance, where the power conversion efficiency (PCE) significantly improved from 3.21% to 20.08% (best PCE is 20.56%) when 0.5 M DMPU (with respect to 1 M of perovskite) was added into the precursor solution.
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25-01-2016Mechanochemistry allows to synthesize a variety of functional hybrid inorganic-organic materials, potentially of great importance for the energy sector. Our youngest children are high quality perovskites. These compounds can be used to produce thin light-sensitive layers of high efficiency solar cells - said Prof. Lewiński.
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This study indicated that the top–down reaction of the perovskite nanostructure can be achieved by a simple solid phase reaction without long-time grinding. 34,36 2. Experimental section 2.1 Materials and instruments Lead (II) bromide (99%), cesium bromide (99.9%) and L-lysine (97%) were purchased from Adamas-beta.
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01-08-2018A high-quality perovskite film with low point defects and grain boundaries is necessary to obtain higher device PCEs. This could greatly avoid the non-radiative recombination which could cause the loss
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generally, high-quality perovskite films are associated with high pl efficiency and slow pl decay with reduced non-radiative recombination. 4,44 the emission peaks corresponding to the maximum pl intensity are located at about ∼775 nm corresponds to the band gap of about 1.6 ev, which is consistent with the previously reported results. 45,46
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07-08-2018Tandem perovskite solar cells are an effective concept to overcome the Shockley–Queisser limit of a single-junction perovskite solar cell. For a high-performance tandem cell, besides a wide-bandgap perovskite top cell, a high-quality low-bandgap perovskite bottom cell with an optimum bandgap of ∼1.2 eV is urgently needed.
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07-02-2021We show high-performance slot-die-coated PSC with comparable PCE values as state-of-the-art lab-scale devices with these advancements. Notably, we observe almost identical PCE values for the multiple pixels distributed over a large area, underlining further the promise for scaled manufacturing of high-quality perovskite thin films.
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Solvent Engineering as a Vehicle for High Quality Thin Films of Perovskites and Their Device Fabrication Small. 2021 May 14;e2008145. doi: 10.1002/smll.202008145 . 1 Department of Electrical and Electronic Engineering, Advanced Technology Institute (ATI), University of Surrey, Guildford, Surrey, GU2 7XH, UK. PMID: 33988287
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Buehler's sectioning, mounting, grinding and polishing, imaging and analysis and hardness testing metallographic equipment along with consumables are used by metallurgical, metallography, petrography,
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01-11-2017In this report, large size and high-quality perovskite 23 CH 3 NH 3 PbI 3 (MAPbI 3 ) single crystals have been prepared us- 24 ing inverse temperature crystallization (ITC) method with care-
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Scientists in the US have now deposited large-area, high-quality perovskite films at 99 mm/s under mild conditions. 'We designed a general solvent mixing so that one can blade-coat continuous, large grain and compact perovskite films at unprecedented speed at room temperature in air,' says team leader Jinsong Huang of the University of North Carolina.
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Solvent-engineering has caused widespread concern in the aspects of improving the high-quality perovskite layers. For the preparation of the cation-anion-mixed perovskite Cs 0.05 (MA 0.17 FA 0.83 ) 0.95 Pb(I 0.83 Br 0.17 ) 3, the influence of the perovskite precursor composition on the quality of perovskite layers is not clear yet.
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Mechanochemistry allows to synthesize a variety of functional hybrid inorganic-organic materials, potentially of great importance for the energy sector. Our youngest children are high quality perovskites. These compounds can be used to produce thin light-sensitive layers of high efficiency solar cells - said Prof. Lewiński.
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14-08-2018The solution-based hot-casting technique, which induces a fast crystallization process of the perovskite, has been demonstrated more efficient to fabricate high-quality perovskite film with
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04-09-2007Figure 1. Specific surface area of various nanoperovskites calcined at 200C. Another advantage of reactive grinding is that it produces mixed oxides consisting of agglomerates of nanocrystalline domains. Their SSA can be increased by partial detachment of the nanoparticles, which yields a looser agglomerate.
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14-08-2018Effects of defects in perovskite films and the device performance of solar cells. Although the metal halide perovskites have shown high defect-tolerance, it is now generally accepted that there
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07-07-2021In 2020–2021, the research activities on perovskite layer mainly focus on stabilizing the formamidinium lead iodide (FAPbI 3) perovskite phase with wide absorption range and long carrier lifetime to boost the short-circuit current density ( JSC) and open-circuit voltage ( VOC) of PSCs [ 25, 26 ].
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15-01-2016Perovskites are not the only group of three-dimensional materials that has been produced mechanochemically by Prof. Lewiński's team. In a recent publication, the Warsaw researchers showed that by
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Although perovskite solar cells have achieved an efficiency over 25%, the scalable fabrication of high efficiency and stable large perovskite solar modules is still a big challenge. To date, various up-scaling methods have been developed to deposit large area perovskite films, but most of them are mainly based on the MAPbI 3 perovskites and a few on the more stable FA-based
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20-12-2018Machine learning has been recently used for novel perovskite designs owing to the availability of a large amount of perovskite formability data. In this study, a procedure Rationalizing Perovskite Data for Machine Learning and Materials Design J Phys Chem Lett. 2018 Dec 20;9(24):6948-6954. doi: 10.1021/acs.jpclett.8b03232.
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26-10-2021Nie et al. (2015) developed the hot-casting process to accelerate the evaporation of the high-boiling solvent to render a high-quality perovskite film and a tunable perovskite morphology by tuning the temperature of the substrate. A vacuum-assisted solvent evaporation method was elaborated by Li et al. (2016).
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However, the preparation of high-quality perovskite films on flexible substrates has still be 1 Key Laboratory for Micro-Nano Physics and Technology of Hunan Province, State Key Laboratory of Chemo/Biosensing and Chemometrics, School of Physics and Electronics, Hunan University, Changsha, Hunan, 410082, P. R. China.
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02-08-2019under this broad goal, the project had four major objectives: 1) develop high-performance pb-based pv devices and study alternative inorganic contact materials to improve the device stability; 2) advance computational techniques to understand the electronic and optical properties of perovskite semiconductors from a theoretical
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Among various PSCs, typical 3D halide perovskite-based PSCs deliver the highest efficiency but they suffer from severe instability, which restricts their practical applications. By contrast, the low-dimensional Ruddlesden–Popper (RP) perovskite-based PSCs have recently raised increasing attention due to their superior stability.
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12-11-2022Researchers from Helmholtz-Zentrum Berlin (HZB) and Potsdam University have reported perovskite–silicon tandem solar cells with periodic nanotextures that offer various advantages without compromising the material quality of solution-processed perovskite layers.
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02-08-2019article{osti_1582433, title = {High Performance Perovskite-Based Solar Cells (Final Technical Report)}, author = {Mitzi, David and Yan, Yanfa}, abstractNote = {Hybrid lead-halide perovskite semiconductors have become one of the most heavily studied photovoltaic (PV) materials within the past ten years. However, these materials
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The researchers characterised the deposits using scanning electron microscopy and x-ray diffraction and then used them to fabricate solar modules with aperture areas above 60cm 2 and efficiencies up to 16.4% – the highest value reported so far for perovskite devices with comparable area.
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13-03-2019Currently, metal halide perovskite nanocrystals have been extensively explored due to their unique optoelectronic properties and wide application prospects. In the present work, a facile grinding method is developed to prepare whole-family APbX 3 (A = MA, FA, and Cs; X = Cl, Br, and I) per
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